Thermal transfer investigation

Key idea: Compare insulation by recording water temperature as it cools. Change one design feature, keep water amount and starting temperature the same, and compare the cooling curves.

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  • SEC G2 Science Physics component 2027
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Which keeps a drink hot longer, a polystyrene cup or a thin plastic one? You can find out by pouring hot water into each and watching how fast it cools. Energy leaves the water by conduction, convection, radiation and evaporation, and many things affect how fast, so a fair test changes one factor, keeps the others the same, and compares the cooling curves. Hot water can scald even below boiling point: use the temperature and apparatus your teacher chooses, on a stable tray.

Choose one factor to investigate

The rate at which hot water loses energy depends on:

  • the temperature difference between the water and the room: for the same set-up, a larger difference generally produces faster cooling;
  • the material of the container: expanded polystyrene contains trapped gas and reduces conduction through the wall;
  • the surface: a matt black coating generally emits infrared more effectively than a bare, polished metal surface at the same temperature;
  • whether there is a lid: a close-fitting lid limits air exchange and evaporation above the water;
  • the surface area, wall thickness and shape of the container.

Choose one factor and keep other relevant conditions as similar as possible. If two cups differ in material, thickness and shape, the result compares cup designs; it does not isolate the effect of material alone. The temperature difference changes during every run. To compare temperature falls over a fixed time, all the cups must start at the same temperature.

To compare insulating materials, you can also wrap identical containers in equal thicknesses of each material, covering the same area and fitting closely. An unwrapped container, set up in the same way, shows how much each material slows the cooling.

Worked example 1

A plan for comparing two cups

Problem

Plan an investigation to find whether a polystyrene cup keeps water hot better than a thin plastic cup.

Show full solution
  1. Variables

    Method

    Independent: which cup design is used. Dependent: the temperature fall over the same elapsed time.

    Reason

    With the same mass of water, temperature fall compares cooling performance. Different cup heat capacities and walls prevent you from treating this as a measurement of the materials’ thermal conductivity.

    Working

    Answer

    Use the same water mass (approximately the same volume at the same starting temperature), similar cup capacities and exposed areas, identical lids, the same room conditions and thermometer immersion. Record unavoidable differences in shape and wall thickness. Read each cup at one-minute elapsed intervals.

  2. Method

    Method

    Measure equal amounts of water using heat-safe apparatus chosen by your teacher. Fit identical lids and support the thermometer bulbs in the water, clear of the walls and bottom.

    Reason

    For water at the same temperature, equal volumes give approximately equal masses. Stir gently so the thermometer represents the bulk water temperature.

    Working

    Answer

    Choose a common starting temperature within your teacher’s approved method. Record each cup’s own start time when it reaches that temperature. Read at elapsed times of 0, 1, 2, …, 10 minutes for that cup; stagger the starts or use two observers so each reading is on time.

  3. Analyse and repeat

    Method

    Plot both cooling curves on one grid and compare the temperature falls over 10 minutes.

    Reason

    One grid makes the comparison direct.

    Working

    Answer

    Repeat the whole comparison to check that the difference is larger than the scatter between runs.

  4. State the comparison

    Working

    Answer

    Compare the temperature falls in 10 minutes from equal starting temperatures and water masses. The cup with the smaller fall keeps its water hotter in this test; repeat before deciding whether the difference is reliable.

Check your understanding 1 Testing a lid

Three identical cups each hold 150 cm³ of water. A has a lid and starts at 80 °C; B has no lid and starts at 70 °C; C has no lid and starts at 80 °C. Choose the fairest comparison and the reason.

Compare
Reason

Show answer

A and C share water volume and starting temperature, so the lid is the changed factor. A and B also differ in starting temperature, which changes cooling even without a lid effect.

Control the water and timing; report differences between cup designsTwo schematic cups with identical lids contain equal water amounts. Each thermometer bulb is immersed near the centre of the water, clear of the cup wall and bottom. Thin plastic and thicker polystyrene walls show why this is a cup-design comparison rather than a test of material alone. Each cup has its own start time when it reaches the common approved starting temperature, and readings are made at equal elapsed intervals. The cups share room conditions.Compare the two designs under matching conditionsCup A: thin plasticsamewateramountstart at common θ₀use this cup's elapsed timeCup B: polystyrenesamewateramountstart at common θ₀use this cup's elapsed timeSame room conditions; bulb clear of walls and bottom.
Control the water and timing; report differences between cup designsTwo schematic cups with identical lids contain equal water amounts. Each thermometer bulb is immersed near the centre of the water, clear of the cup wall and bottom. Thin plastic and thicker polystyrene walls show why this is a cup-design comparison rather than a test of material alone. Each cup has its own start time when it reaches the common approved starting temperature, and readings are made at equal elapsed intervals. The cups share room conditions.Compare the two designs under matching conditionsCup A: thin plasticsamewateramountstart at common θ₀use this cup's elapsed timeCup B: polystyrenesamewateramountstart at common θ₀use this cup's elapsed timeSame room conditions; bulb clear of walls and bottom.
Match water amounts, lids, room conditions and starting temperature. Compare equal elapsed times from each cup’s own start; report shape and wall-thickness differences.

These constructed example readings use 150 cm³ of water in each cup, starting at 80.0 °C, in a room at 27 °C. Use them to practise analysing cooling; they are not measurements from an experiment.

t / minplastic cup θ / °Cpolystyrene cup θ / °C
080.080.0
177.579.0
275.078.0
373.077.0
471.075.5
569.074.5
667.074.0
765.073.0
863.572.0
961.571.0
1060.070.0

For this example, a thermometer with 1 °C divisions is read by interpolation and readings are recorded to the nearest 0.5 °C. Check the thermometer specification when assessing measurement uncertainty.

Cooling curves for two cups

Two cooling curves of water temperature in °C against time in minutes from 0 to 10 minutes. Both start at 80.0 °C. The plastic-cup curve, drawn solid with circles, falls more steeply than the polystyrene-cup curve, drawn dashed with squares. The data table lists every reading.

Scroll across the figure to read all labels.

Two cooling curves of water temperature in °C against time in minutes from 0 to 10 minutes. Both start at 80.0 °C. The plastic-cup curve, drawn solid with circles, falls more steeply than the polystyrene-cup curve, drawn dashed with squares. The data table lists every reading.Two cooling curves of water temperature in °C against time in minutes from 0 to 10 minutes. Both start at 80.0 °C. The plastic-cup curve, drawn solid with circles, falls more steeply than the polystyrene-cup curve, drawn dashed with squares. The data table lists every reading.
Constructed example readings for 150 cm³ of water starting at 80.0 °C in each of two cup designs with identical lids, in a room at 27 °C. The comparison concerns these cup designs.
Open full-size graph
What to noticeThese are constructed analysis readings, not reported measurements. Segments join the supplied points; on paper, draw a smooth best-fit trend. Recording to 0.5 °C does not establish the full uncertainty. The vertical axis starts at 50 °C.
View figure data
Figure data: Cooling curves for two cups
Time t (min)Plastic cupPolystyrene cup
080.080.0
177.579.0
275.078.0
373.077.0
471.075.5
569.074.5
667.074.0
765.073.0
863.572.0
961.571.0
1060.070.0

On paper, draw a smooth best-fit curve following each trend rather than forcing it through every point. The displayed segments connect the example readings. Cooling generally slows as water approaches room temperature; individual rounded readings can scatter around that trend.

Worked example 2

Comparing the cooling curves

Problem

Use the readings to compare the two cups and write a conclusion.

Show full solution
  1. Temperature fall in 10 minutes

    Method

    Subtract the final reading from the starting reading for each cup.

    Reason

    Both started at 80.0 °C and were read over the same time, so the falls can be compared directly.

    Working

    Answer

    Plastic: 80.0 − 60.0 = 20.0 °C. Polystyrene: 80.0 − 70.0 = 10.0 °C.

  2. Average rate of cooling

    Method

    Divide each fall by the time.

    Reason

    A rate makes the comparison clear in one number per cup.

    Working

    Answer

    Plastic: 20.0 ÷ 10 = 2.0 °C/min. Polystyrene: 10.0 ÷ 10 = 1.0 °C/min.

  3. Interpret the difference

    Method

    Over these 10 minutes, the water in the polystyrene cup had half the average rate of temperature decrease.

    Reason

    Expanded polystyrene can reduce conduction through the wall. However, these cups also differ in design, and temperature changes alone do not separate conduction, convection, evaporation and radiation.

    Working

    Answer

    “Under these conditions, the tested polystyrene cup kept its water hot for longer: its water fell by 10.0 °C in 10 minutes compared with 20.0 °C for the plastic cup.”

  4. State the conclusion

    Working

    Answer

    Under these conditions, the polystyrene cup kept its water hotter: it cooled by 10.0 °C rather than 20.0 °C in 10 minutes. Its average cooling rate was 1.0 °C/min, compared with 2.0 °C/min for the plastic cup.

Check your understanding 2 Find a rate over the stated interval

Show the steps Optional working
Unit: °C
Unit: °C/min

Show answer

The temperature fall is 75.0 − 63.0 = 12.0 °C, so the average rate of cooling is 12.0/8.0 = 1.5 °C/min. The instantaneous cooling rate can change during the interval.

Guided practice 3

A comparison that is not fair

About 5 min

Problem

Cup C starts at 90 °C and reaches 70 °C at 12 minutes and 60 °C at 20 minutes. Cup D starts at 70 °C and reaches 60 °C at 10 minutes. The water masses and room conditions are equal. Which intervals should you compare, and which cup keeps the water hot longer over that range?

Explain, then improve

Unit: min
Unit: min
Water stays hot longer over this range

Hints

Hint 1

what else changed?

Find a temperature range that both cups pass through.

Hint 2

same temperature range

Subtract the two elapsed times for cup C. Cup D begins at the top of the shared range.

Show solution step by step
  1. Choose matching temperatures

    Method

    Compare cooling from 70 °C to 60 °C.

    Reason

    Both cups pass through this range, so they can be compared at matching temperature differences from the room. Their full runs begin at different temperatures and do not give that comparison.

    Working

    Answer

    For C, use the interval from 12 to 20 minutes. For D, use the interval from 0 to 10 minutes.

  2. Compare the cooling times

    Method

    C takes 8 minutes; D takes 10 minutes.

    Reason

    Taking longer to cool through the same range means the water stays hotter longer under these conditions.

    Working

    Answer

    C: 20 - 12 = 8 minutes. D: 10 - 0 = 10 minutes. D takes 2 minutes longer.

  3. State the comparison

    Working

    Answer

    Cup D keeps the water hot longer over 70 °C to 60 °C in this test. Compare matching temperature ranges with equal water masses and room conditions, and repeat the test before deciding whether the difference is reliable.

Evaluate the method

SourceEffectImprovement
Water cools while it is poured and the lids fittedThe cups do not start at the same temperatureRecord each cup’s start time at the agreed common starting temperature.
Thermometer bulb touching the side of the cupIt can be influenced by the wall, rather than represent the bulk water temperatureHold the thermometer through the lid so that the bulb is in the middle of the water.
Water hotter at the top than the bottomReadings depend on where the bulb isStir gently before each reading.
One person reading two cups at the same momentReadings are late or rushedStagger start times and use each cup’s elapsed-time schedule, or use two observers.
A draught from a fan or window on one cupThat cup cools faster for a reason other than its designPlace both cups side by side, away from fans and windows.
A small difference between the cupsIt may be smaller than the scatter between runsRepeat the comparison and check that the difference appears each time.

Test another factor. Use the same method to investigate the surface: compare identical metal cans with different outside surface treatments: one matt black and one bare, polished metal. Keep water mass, lids, exposed area and starting temperature the same. Compare the effect of the surface treatment on total cooling. Conduction, convection and evaporation also occur. A matt black coating usually emits infrared more strongly than polished metal; visible colour alone is an unreliable guide.

Check your understanding 3 Identify the controlled variable

In an investigation of how surface treatment affects cooling, which of these is a control variable?

Show answer

Keep the water volume the same at the common starting temperature, giving approximately equal water masses. Surface treatment is the changed independent variable; temperature after ten minutes is measured. Also match lids, geometry, room conditions and the reading method. A cooling comparison does not separate radiation from all other transfers.

Check your understanding 4 Insulation with cold water

Each container starts with the same mass of water at 5.0 °C in a 27 °C room. After 10 min, A reaches 13.0 °C and B reaches 9.0 °C. Find the average warming rates. Which keeps water colder, and which way is energy transferred?

Show the steps Optional working
Unit: °C
Unit: °C/min
Show the steps Optional working
Unit: °C
Unit: °C/min
Keeps water colder
Energy transfer

Show answer

A warms at (13.0 − 5.0)/10 = 0.80 °C/min; B warms at (9.0 − 5.0)/10 = 0.40 °C/min. B keeps water colder. Both samples gain energy from the warmer room; insulation slows that transfer.

Check your understanding 5 Explain insulation in both directions

Explain why insulation can keep hot water hot and cold water cold. Use the direction of energy transfer in each case.

Show answer

Energy leaves hot water for cooler surroundings, but enters cold water from warmer surroundings. Insulation slows energy transfer in either direction, so it reduces both cooling of hot water and warming of cold water.

Common mistakes

  • Comparing temperature falls from different starting temperatures.
  • Changing more than one thing at once, such as the cup material and its shape, and crediting the result to one of them.
  • Saying “cold” enters the cup. Energy leaves the hotter water for the cooler surroundings.
  • Claiming one material always insulates better from a test of two particular cups.
  • Letting the thermometer bulb touch the side of the cup, or reading without stirring.

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