A Level Thermal Physics Hub

A Level Physics thermal hub: thermodynamic temperature, ideal gases, kinetic theory, internal energy, thermodynamic laws, heat capacity and latent heat.

  • GCE A-Level H2 Physics 2027
Learning goals
  • Use thermodynamic temperature and convert between Celsius and kelvin.
  • Use ideal-gas equations with particles, moles and SI units.
  • Apply the kinetic model to gas pressure and mean translational kinetic energy.
  • Derive pV = ⅓Nm⟨c²⟩ from the definition of pressure and a one-dimensional model of molecular collisions extended to three dimensions.
  • Relate microscopic energy, internal energy and thermal equilibrium.
  • Apply work conventions and the zeroth and first laws of thermodynamics.
  • Define and use heat capacity and specific heat capacity in energy balances.
  • Define and use specific latent heat in phase-change energy balances.

Thermal Physics links measurable states such as pressure, volume and temperature to microscopic energy and particle motion. The route below separates gas-model assumptions, energy stores, energy transfers and phase changes so that each equation is used with the correct system and conditions.

Start here

Understand first: revise energy transfers and changes of state in O Level Thermal Physics, then review momentum change in Kinematics before the kinetic-theory derivation.

Common mark-loss errors: using Celsius in gas equations, mixing n with N, treating heat as stored energy, changing the meaning of work in the first law, and combining temperature-change and phase-change stages into one equation.

Move to structured work when: you can define the system, name each transfer, state the work convention and write one energy term for every stage of a thermal process.

Lessons

Work through these lessons in order.

  1. Thermodynamic temperature and Celsius conversion
  2. Ideal-gas equations, particles and moles
  3. Kinetic model, pressure derivation and molecular energy
  4. Internal energy, temperature and thermal equilibrium
  5. Work, zeroth law and first law
  6. Specific heat capacity and specific latent heat
  7. Thermodynamic Temperature Scale (Kelvin)

    Learn what makes the Kelvin scale an absolute thermodynamic temperature scale and how to convert between Celsius and kelvin for A Level Physics.

  8. Ideal Gas

    Learn the ideal gas equation of state pV = NkT and how to use it in calculations with moles, particles and SI units (A Level Physics).

  9. Pressure in gases: Boyle’s law

    Learn Boyle’s law for a fixed mass of gas: absolute pressure, isothermal compression, p–V graphs, particle reasoning, and worked A Level examples.

  10. Kinetic Theory of Gases

    Derive pV = (1/3)Nm⟨c^2⟩ from the particle model, connect it to pV = NkT, and solve kinetic theory questions (A Level Physics).

  11. Thermodynamic Systems

    Internal energy, thermal equilibrium (zeroth law), and work done by/on a gas (W = pΔV) for A Level Physics.

  12. First Law of Thermodynamics

    Apply the first law of thermodynamics ΔU = Q + W (work done on the system), including constant-volume and constant-pressure (pΔV) cases (A Level Physics).

  13. Specific Heat Capacity

    Define and use heat capacity and specific heat capacity, solve energy-balance problems, and evaluate an electrical heating experiment.

  14. Specific Latent Heat

    Define and use specific latent heat, interpret constant-temperature phase changes, and solve multi-stage thermal energy balances.

  15. Questions for Thermal Physics (JC) Set 1

    A Level Physics thermal physics practice questions (JC Set 1), with worked answers.

  16. Questions for Thermal Physics (JC) Set 2

    More A Level Physics thermal physics practice questions (JC Set 2), with worked answers.

Revision

Quick Reference
Law / QuantityFormulaUnit
Ideal Gas LawpV = nRT or pV = NkT-
Mean KE⟨Eₖ⟩ = (3/2)kTJoule (J)
First law (work sign defined)Δ U = Q + WₒₙJ
Constant-pressure workW_by = pΔ V; Wₒₙ = -pΔ VJ
Specific heat capacityQ = mcΔ TJ kg⁻¹ K⁻¹
Specific latent heatQ = mlJ kg⁻¹

Constants: R = 8.31 J mol⁻¹K⁻¹, k = 1.38 × 10⁻²³ J K⁻¹

Exam templates (fast marks)

1) Gas law conversions

  1. Convert temperature to Kelvin: T = θ + 273.15.
  2. Convert units consistently (Pa, m³, mol).
  3. Use pV = nRT (moles) or pV = NkT (molecules), not both.

2) First law questions

  1. State the sign convention you are using (this hub uses Δ U = Q + W where W is work done on the gas).
  2. Identify the process (isothermal, isobaric, isochoric, adiabatic) if given.
  3. Use W_by = pΔ V only when the external pressure is constant, and reverse its sign for Wₒₙ.
  4. Use special cases: isochoric Δ V = 0 ⇒ W = 0; isothermal ideal gas Δ U = 0.
Graph Skills (Exam + Practical)

Absolute zero from a pressure–temperature graph

At constant volume, the ideal gas law implies p ∝ T (Kelvin). If you plot pressure against temperature in °C and extrapolate, the line hits p = 0 at about -273.15°C.

Gas pressure vs temperature (constant volume)

A straight-line p–θ plot that extrapolates to zero pressure at about −273 °C, illustrating absolute zero.

Scroll across the graph to read all labels.

A straight-line p–θ plot that extrapolates to zero pressure at about −273 °C, illustrating absolute zero.A straight-line p–θ plot that extrapolates to zero pressure at about −273 °C, illustrating absolute zero.
The straight-line relationship comes from p ∝ T (in Kelvin). The x-intercept gives an estimate of absolute zero.
Open full-size graph
View figure data
Values and uncertainty for Gas pressure vs temperature (constant volume)
SeriesTemperature, θ (°C)Temperature, θ uncertaintyPressure (scaled)Pressure uncertainty
Readings (scaled)-2000.27
Readings (scaled)-1000.63
Readings (scaled)01
Readings (scaled)501.18
Readings (scaled)1001.37
Best-fit (extrapolated)-273.150
Best-fit (extrapolated)1001.37
What You Must Memorise
  • Ideal Gas Assumptions: Random motion, negligible volume of particles, elastic collisions, negligible forces between collisions.
  • Absolute Zero: The temperature at which gas pressure/volume extrapolates to zero (0K or -273.15°C).
  • Internal energy: the sum of microscopic kinetic and potential energies associated with the particles of a system.
  • First Law: The increase in internal energy equals the heat supplied plus work done on the system.
  • Isothermal: Constant temperature (Δ U = 0 for ideal gas).
  • Adiabatic: No heat transfer (Q = 0).
Top Exam Traps
  1. Work Sign Convention: Be VERY careful. Is it work done ON the gas (+W, compresses) or BY the gas (-W, expands)? The formula Δ U = Q + W assumes work ON.
  2. Temperature Unit: Always convert ° C to Kelvin for gas laws (T = θ + 273.15).
  3. rms Speed: square root of (⟨c²⟩) is the root-mean-square speed. ⟨c⟩² is the square of the mean speed. They are not the same.
  4. Internal Energy: For an ideal gas, U depends only on Temperature. If T is constant (isothermal), Δ U = 0.
  5. Mole vs Molecule: Don’t mix up n (moles, use R) and N (molecules, use k).

Practice

Practice (Quiz + Structured Questions)

Use the two quizzes to diagnose gaps: the temperature and ideal gases quiz checks Kelvin temperature, the gas equations and kinetic theory, and the thermodynamic systems quiz checks internal energy, work done on a gas and the first law. Then complete the structured set without formula prompts:

A Level Temperature & Ideal Gases QuizA Level Thermodynamic Systems QuizThermal Physics Structured SetA Level Quiz Hub

The two legacy JC sets remain available for extra questions: Set 1 and Set 2.

Next hub: Electric Fields

Back To A Level Physics

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Course and syllabus information
Course
GCE A-Level H2 Physics
Edition
GCE A-Level H2 Physics 2027